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All answers having "Principal" as clue:

3 Character Answers:

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TOP



4 Character Answers:

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ARCH

HEAD

HIGH

LEAD

MAIN

STAR



5 Character Answers:

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CHIEF

FIRST

GRAND

MAJOR

MORAL

PRIME



6 Character Answers:

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LYCHEE

STAPLE



7 Character Answers:

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CENTRAL

LEADING

PRIMATE

SALIENT



8 Character Answers:

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FOREMOST



10 Character Answers:

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HEADMASTER