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All answers having "Madam" as clue:

3 Character Answers:

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EVE



4 Character Answers:

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ADAM

BAWD

IUSE

LADY



5 Character Answers:

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USENO



7 Character Answers:

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SIGNORA



8 Character Answers:

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MEMSAHIB



10 Character Answers:

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LEILADYLEI