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All answers having "Unmatched" as clue:

3 Character Answers:

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ODD

ONE

RHO



4 Character Answers:

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AONE

BEST

LONE

ONER

SOLE



5 Character Answers:

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ALONE



6 Character Answers:

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UNIQUE



7 Character Answers:

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SUPREME



8 Character Answers:

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PEERLESS