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All answers having "Matchless" as clue:

3 Character Answers:

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ODD

ONE



4 Character Answers:

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BEST

SOLE



5 Character Answers:

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ALONE

GREAT

UNWED



6 Character Answers:

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IGUANA

UNIQUE



8 Character Answers:

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UNPAIRED



9 Character Answers:

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NONPAREIL



10 Character Answers:

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INIMITABLE



12 Character Answers:

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INCOMPARABLE

SECONDTONONE

UNPARALLELED

WITHOUTEQUAL



13 Character Answers:

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BEYONDCOMPARE

ONEINAMILLION