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All answers having "Highlander" as clue:

3 Character Answers:

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RHO



4 Character Answers:

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CELT

GAEL

SCOT



5 Character Answers:

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KILTY

LAIRD



6 Character Answers:

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KILTIE



8 Character Answers:

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CLANSMAN

PLAIDMAN

SCOTSMAN



10 Character Answers:

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CALEDONIAN