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All answers having "High muck-a-muck" as clue:

3 Character Answers:

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NOB

VIP



4 Character Answers:

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EXEC



5 Character Answers:

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MOGUL

NABOB



6 Character Answers:

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BIGWIG



9 Character Answers:

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BIGCHEESE



11 Character Answers:

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GRANDPOOBAH