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All answers having "Captivate" as clue:

3 Character Answers:

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AWE

ELK

RAG

RHO

WIN



4 Character Answers:

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ARID

LESS

POST



5 Character Answers:

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CHARM

ERASE

SWING



6 Character Answers:

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DISARM

ENAMOR

ENANOR

ENDEAR

ENGAGE

RAVISH

RELISH

TOOBAD

VESTRY



7 Character Answers:

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ATTRACT

BABYISH

BEGUILE

BEWITCH

EASEOFF

ENAMOUR

ENCHANT

ENGROSS

ENTHRAL

ROPEDIN



8 Character Answers:

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ENTHRALL

ENTRANCE

INTRIGUE

TEABREAK



9 Character Answers:

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DIFFICULT

FASCINATE