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All answers having "24/7" as clue:

3 Character Answers:

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RHO



4 Character Answers:

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EVER

OPEN



6 Character Answers:

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ALWAYS



7 Character Answers:

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ANYTIME

NONSTOP



10 Character Answers:

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ATALLTIMES

DAYORNIGHT



13 Character Answers:

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ROUNDTHECLOCK